The specific fields to focus on will differ depending on the type of issue being troubleshoot but important ones to be aware of are : - the r/s and w/s for knowing how many read and write requests per second, respectively, are being issued - the r_await and w_await for knowing the delay between the read and write requests being issued and when they are served - %util for knowing the percentage of elapsed time during which I/O requests were issued to the device.
The command man iostat can provide much more information for how to use the command and understand the information it provides.